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VLE IN BINARY
MIXTURE
Vaporization Equilibrium
Ratio
1
VLE FROM K-VALUE CORRELATIONS
Pi sat
Ki yiP xiPisat (3.14)
P
i Pi sat
Ki (3.15)
P
3
According to Eq. (3.13) :
y i K i xi
K i xi 1 (3.16a)
i
yi 1
i
yi
xi
Ki yi
1 (3.16b)
i Ki
xi 1
i
4
Bubble point calculation
xi are known,
the problem is to find the set of K-
values that satisfies Eq. (3.16a).
K i xi 1 (3.16a)
i
5
Dew point calculation
yi are known,
the problem is to find the set of K-
values that satisfies Eq. (3.16b):
yi
1 (3.16b)
i Ki
6
Methane
P = 250 Psia
T = 180F
8
EXAMPLE 3.13
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SOLUTION 3.13
a. When the system is at its dew point, only an
insignificant amount of liquid is present, and
the given mole fractions are values of yi.
P = 6.9 bar P = 10.34 P = 8.7 bar
i yi bar
Ki yi/Ki Ki yi/Ki Ki yi/Ki
CH4 0.10 20.00 0.005 13.20 0.008 16.00 0.006
C2H6 0.20 3.25 0.062 2.25 0.089 2.65 0.075
C3H8 0.70 0.92 0.761 0.65 1.077 0.762 0.919
yi Ki
i 0.828 1.174 1.000
P = 8.7 bar
10
11
b. When the system is almost condensed, it is
at its bubble-point, and the given mole
fractions are values of xi.
P = 26.54 bar
12
Flash Calculations
(at given T and P)
13
Total Mass Balance:
F L V
Component Mass Balance:
zi F xi L y iV (i = 1, 2, , N)
L V (i = 1, 2, , N)
zi xi y i
F F
z i x i 1 y i (i = 1, 2, , N) (3.14)
V
where
F 14
L V
zi xi y i V
F F
F
F V V F L V
zi xi yi
F F
F V V
zi xi yi
F F F
z i x i 1 y i
z i x i 1 y i
15
yi
According to eq. (3.13): xi , hence
Ki
yi 1
zi 1 y i y i
Ki Ki
z i 1 1 K i 1 K i 1
yi Ki Ki Ki
zi K i
yi (3.15)
1 K i 1
16
Since i yi =1, eq. (3.15) is summed up all
over species:
zi K i
1 (3.16)
i 1 K i 1
17
EXAMPLE 3.14
The system acetone (1)/acetonitrile (2)/
nitromethane (3) at 353.15 K and 110 kPa
has the overall composition, z1 = 0.45, z2 =
0.35, z3 = 0.20. Assuming the Raoults law
is appropriate to this system, determine ,
{xi}, and {yi}. The vapor pressures of the
pure species at 353.15 K are
P1sat = 195.75 kPa
P2sat = 97.84 kPa
P3sat = 50.32 kPa
18
SOLUTION 3.14
132.40 kPa
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Second, do DEW P calculation with {zi} =
{yi) to find Pdew.
1 1
Pdew
yi y1 y2 y3
sat
sat sat
i
sat
Pi P1 P2 P3
101.52 kPa
Eq. (2.16):
zi K i
1
i 1 K i 1
21
0.451.7795 0.35 0.8895
1 0.7795 1 0.1105
0.20 0.4575
1
1 0.5425
0.737
zi K i yi
yi xi
1 K i 1 Ki
y1 = 0.5087 x1 = 0.2859
y2 = 0.3389 x2 = 0.3810
y3 = 0.1624 x3 = 0.3331 22
z i x i 1 y i
zi xi xi y i
zi xi y i xi
zi xi y i xi
zi xi
y i xi
z1 x1 0.45 0.2859
0.7365
y1 x1 0.5087 0.2859
23
24
Algoritma:
1. Input: zi, xi, P
2. Hitung i
3. Tebak T
4. Hitung P1sat dan P2sat y i i Pi sat
Ki
5. Hitung Ki xi P
6. Hitung yi
7. Hitung f(y)
8. Jika f(y) 0, kembali ke langkah 3
25
z i x i 1 y i
zi xi xi y i
zi xi y i xi
zi xi
y i xi
26
z1 x1
y1 x1
z1 x1 z2 x2
y1 x1 y2 x2
z2 x2
y2 x2 z1 x1 z2 x2
f y 0
y1 x1 y2 x2
27