XY DNG

CNG THC PHA CH

 Mc ch
Sn phm c cht lng p ng yu
cu s dng.
Ph hp iu kin cng ngh, thit
b.
Chi ph ph hp gi c sn phm.
 iu kin cng ngh
Cn trn ( nht yu cu).
p n.
Cn trng.
Lu ho (p khun, p chuyn, p
tim).
iu kin lu tr bn thnh phm.
 My mc thit b
Cc thng s k thut ca thit b
 Chi ph sn xut
Chn nguyn liu p ng yu cu
vi gi thp nht.
Hn hp an ton (khng t lu trong
gia cng), thi gian lu ho ngn
(nng sut).
Tm li, sn phm c gi c hp l, khch hng
chp nhn c.
 THNH PHN C BN

1 - Cao su: NR,

2 - H lu ho: S, activators,
accelerators
3 - H n (fillers): C en, CaCO3,
4 - H bo v (chng lo ho)
5 - H lm mm (processing aids)
6 - Cc cht khc: mu, to xp, mi
 1 - CAO SU

Yu cu
Khong nhit lm vic ca sn phm.

Kh nng khng dung mi.

Kh nng khng ho cht

Kh nng khng lo ho thi tit

Cp s dng (gi c).

 Nhit lm vic

-70 - +80 oC BR
-50 - +70 oC NR, IR
-40 - +85 oC SBR
-20 - +100 oC NBR, CR
-40 - +110 oC IIR
-40 - +130 oC EPDM
-70 - +170 oC VMQ
 cng

Cao su (phr) cng

(Shore A
NBR, CR +44
NR, SBR +40
IIR +35
SBR (37,5% du) +26
 khng ho cht

Bng photocopy nh km
 2 - CHT TR XC TIN
(activators)
ZnO liu lng t 3 5 phr
Stearic acid liu lng t 1 2 phr
 3 - CHT XC TIN
(accelerators)
Chn cht xc tin v liu lng ph
thuc:
- Tnh cht sn phm
- iu kin gia cng v lu tr.
- Nng sut lu ho.
Cn phi hp nhiu cht xc tin.
 4 - H N (fillers)
Da vo yu cu tnh nng c l v gi c:

- Sn phm chu mi mn: SAF, ISAF

- Sn phm chu mi mn nhng to nhit
thp: HAF, ISAF LS (N285).
- Sn phm p n: FEF (N 550), SRF
(N770, N 990).
- Phi hp than en v kaolin, CaCO 3
 cng
khi dng cht n
Cht n cng (Sh A)
FEF, HAF + phr x
ISAF + phr x + 2
SAF + phr x + 4
SRF + phr x 1/3
Kaolin cng + phr x
CaCO3 + phr x 1/7
Du - phr x
 5 - CHT CHNG GIM CP
(antidegradants)
Liu lng t 1 2 phr.
C th phi hp nhiu cht bo v.

VD: Sn phm ngoi tri c th phi

hp cht chng oxy ho nhit vi
cht chng ozone tc kch.
Sn phm mu, cn cht bo v
khng bin mu hay nhum bn.
 CHT BO V VT L
Cc loi sp (wax) phun ra b mt sn
phm bo v di tc ng nh sng, thi
tit, ozone.
Chn sp c nhit nng chy ph hp nhit
lm vic ca sn phm.

VD: Antilux 110 c nhit nng chy 60 64

oC, nhit lm vic sn phm c th n

40 oC.
 CHT LM MM
Ch n tnh tng hp ca cao su vi
cht lm mm

Vi sn phm mu trnh dng cht lm

mm, nu c ch dng du paraffinic.
Vi sn phm s dng nhit thp

dng du paraffinic tt hn.

Vi sn phm chu nhit, dng du c

nhit si cao hn.

 tng hp

NR SBR BR CR EPDM IIR NBR

Du paraffinic + + + - + + _
Naphthenic + + + 0 + 0 0
Aromatic + + + + 0 - 0

+ Tng hp
- Tng hp c gii hn
0 Khng tng hp.
 Ch khi dng cht lm
mm
Kh nng trch thot ra ngoi gy ra
hin tng phun sng hay cng dn
sn phm.
Xu hng ngy nay dng cht lm
mm t cao su gim cp nh LNR
(liquid natural rubber) hay LNBR h
tr qu trnh gia cng m khng suy
gim tnh nng c l sn phm
 CC CHT KHC
Chn mu, ch kh nng chu nhit
ca mu trong qu trnh lu ho nht
l cc mu hu c.
Cht to xp, cn lu n nht
cao su, mi gy kh chu cho ngi
s dng.
 Cng thc pha ch
Va l mt khoa hc va l mt ngh
thut.
Da trn 100 phn khi lng cao su
(phr)
 TNH KHI LNG RING
L THUYT
Khi lng Khi lng ring Th tch
SVR 20 100,00 0,92 108,70
S 3,00 2,07 1,41
ZnO 5,00 5,60 0,89
Stearic acid 2,00 0,85 2,35
CBS 1,00 1,30 0,77
Than en 45,00 1,80 25,00

Tng cng 156,00 139,12

Khi lng ring: 156,00/139,12 = 1,12 (kg/dm3)

 TNH KHI LNG TNG
THNH PHN HN HP SN
XUT
S dng my trn kn dung tch 100 lt, h s s dng bung trn l
80%.
Khi lng m trn: 100 x 80 x 1,12 = 89,6 Kg

SVR 20 100 x 89,6 : 156 = 57,43 Kg

S 3 x 89,6 : 156 = 1,72 Kg
ZnO 5 x 89,6 : 156 = 2,87 Kg
Stearic acid 2 x 89,6 :156 = 1,15 Kg
CBS 1 x 89,6 :156 = 0,57 Kg
Than en 45 x 89,6 :156 = 25,84 Kg
 TNH GI HN HP
Thng tnh gi/n v khi lng :
n gi khi lng.
Khi iu chnh pha ch, vi cht n
c khi lng ring ln nh kaolin,
gi theo khi lng khng th hin
y nn cn c gi theo n v
th tch.
 Gi theo n v th tch

n gi theo th tch = n gi theo

khi lng x khi lng ring.
 TM LI
Pha ch ch cn p ng ng yu cu
Quan tm qu trnh gia cng v yu t kinh
t.
C th phi hp nhiu loi cao su, ho cht.
Khi iu chnh cng khng dng lu
hunh (dng cht n hay cht lm mm)
Bin ng sn xut gii quyt bng cng
ngh, khng lm dng iu chnh pha ch.