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BI GING TH 3

CN DO V CN
TRN HN HP CAO
SU
CAN DEO ( mastication
or polymer breakdown)
Bc au tien cua qua trnh
phoi tron
Can thiet cho cao su thien
nhien ( o deo khong ong
eu) hay trong trng hp phoi
tron cac cao su khac nhau ( o
deo ban au khac nhau)
Tang kha nang can deo
Can biet yeu cau tng hn hp cao
su, thi gian can tron hoa chat phu
gia va cac chat on e xac nh
qui trnh can deo.
Cac yeu to anh hng en qua
trnh can deo:
- Moi trng
- Nhiet o
- T toc truc.
- Van toc dai cua truc.
- Ap lc
- Dung tch
Thiet b:

- may can h hai truc


- May can h bon truc
- May tron kn ( kneeder, internal
mixer).
- Tron kn dang vt xoan.
Vi may can hai truc:
- ep thong qua khe h nho hai
truc
Vi tron kn:
- Nhiet
- Dung tch (h s lp ay)
- Thi gian
Qui trnh c xac nh thong
qua kiem tra o deo wallace
hay o nht Mooney .
CAN DEO SBR
Khac vi NR, s luyen SBR t thay
oi tnh nang c ly SP
Co the dung phong lao e
gi cau truc day thang.
Co the dung chat hoa deo
rut ngan thi gian can deo.
Khong ton tr lau hn 24 gi
CAN DEO BR
Kho can deo, nhat la tren may
can h, chu y nhiet ( < 40 o).
Thng phoi hp vi NR.
Qui trnh can deo va tron hon
hp ke tiep nhau va thng phoi
hp can tron vi than en.
Chat hoa deo va phong lao gi
khong thay oi cau truc, tang o
deo.
CAN DEO CAO SU BUTYL
Thng dung may tron kn,
nhiet o cao (150 1700C trong 5
phut) ket hp than en va cac
chat lam mem.
Can than khi dung may can
h do tnh dnh truc
CAN DEO CAO SU
ACRYLONITRIL BUTADIENE
Do t deo, phat nhiet khi can.
C ly khe truc nho.
Truc giai nhiet tot.
Co the them DOP, DBP hoa
deo.
CAN DEO CAO SU
NEOPRENE, HYPALON,EPDM
Neoprene nhay nhiet, o deo tang khi
nhiet o tang nhng de t lu khi cho
ZnO.
Nen dung nhiet thap, ket hp srearic
chong dnh truc va phong lao chong
thay oi cau truc cao phan t.
Cao su Hypalon, EPDM khong can can
deo hay ch can can deo ngan.
CAN TRON HON HP
CAO SU
Giai oan ke tiep sau can deo.
Cac yeu cau:
- Phan tan that eu chat on,
hoa chat
phu gia.
- Tranh giam cap cao su qua nhieu
dan
en suy giam tnh nang c ly.
Cac yeu to anh hng
en qua trnh can tron
hon hp
Ban chat cao su (phan cc, khong phan cc,de
cat mach, mach nhanh.)
o deo cao su.
Kha nang phan tan hoa chat phu gia, chat
on.
Trnh t cho vao cac chat theo nguyen tac chat
kho phan tan cho vao trc, chat phong lao
oi
vi SBR, BR.
Kiem soat nhiet trong qua trnh can tron.
THIET B
Giong thiet b can deo.
oi vi may can h, t toc thap
hn
( 1:1,06 1: 1.1) . Dung tch: V= 0.65 D. L
oi vi may tron kn, dung tch phu
hp dung tch buong tron bao am
ap lc. Nhiet o va thi gian bao
am me cao su ong eu, khong
giam cap.
CAC BC THC HIEN
Nen chia lam nhieu bc:
- Bc 1( masterbatching): thng cho chat on,
hoa chat phu gia (ngoai tr cac chat tham gia
phan ng khau mach nh lu huynh, xuc tien,
peroxide.), xuat tam, lam nguoi nhanh.
- Bc 2 ( remilling): tron eu me luyen bc
1, nhat la trong trng hp on than en hay
cac chat on kho phan tan, o nht cao.
- Bc 3 ( Finish mixing): cho cac chat
tham gia khau mach, lam nguoi
nhanh, ton tr, cat mau kiem tra
o deo, tnh nang c ly.

Thi gian ton tr khong qua lau


nhat la trong ieu kien nong,
am.
CAN TRON HON HP
NR
Cao su van tiep tuc cat mach trong
qua trnh can tron nen nhiet o va
thi gian anh hng nhieu en chat
lng hon hp.
S dung hoa chat phu gia dang rubber
bound giup phan tan de dang va rut
ngan thi gian.
Dung cac bc can tron.
Lam nguoi nhanh hon hp cao su.
CAN TRON HON HP
SBR
Tranh keo dai thi gian do de tao
gel
Me tron nen t hn so vi NR

Nen phoi hp than vi stearic acid

hay stearate kem giup than phan


tan de hn.
Can tron nhieu bc hieu qua

hn.
CAN TRON HON HP
BR
Nen dung may tron kn.
Dau lam mem cho trc

giup than en phan tan tot,


giam thi gian can tron.
Kiem tra o nht Mooney sau

can deo va sau khi tron hon


hp.
CAN TRON HON HP CAO
SU BUTYL
Nen dung may tron kn vi dung tch nhieu
hn 10% so vi NR va dung nhieu bc
Nhiet co the t 150180 o C vi internal
mixer.
Chat lu hoa cho vao bc sau cung, hay
tren may can h, nhiet o khong qua 105
o C.
Vi may can h nen dung phng phap
moi: dung t cao su, nhieu on, khe truc nho,
lanh. Sau o ni khe truc, cho dan cao su vao.
CAN TRON HON HP
NBR
La cao su khong ket tinh khi keo
cang, chat on va hoa chat phu
gia phai phan tan that tot, mi
at hieu qua tnh nang c ly.
Chu y phan tan lu huynh that

tot do kha nang tan rat t trong NBR.


Nen dung hoa chat dang rubber

bound.
CAN TRON HON HP CAO
SU CHLOROPRENE
( NEOPRENE)
Nhiet o thap, thi gian ngan
Oxyd kim loai, xuc tien cho vao

bc sau cung tranh t lu.


Nen dung phng phap tron

cac hon hp chu tranh t lu.


CAN TRON HON HP
CAO SU HYPALON
Co the thc hien tren may
can h.
Nhiet do thap.

Gi cho o am thap nhat.


CAN TRON HON HP CAO
SU EPDM
S dung may tron kn tot
hn.
Nen cho chat on vao au

giai oan tron.


Dung tch me tron nen hn 10

-15% so vi dung tch buong


can.
Cao Tnh cht gia
Nhit trn Ghi ch
su cng

NR Tt, nhng cn Bt u:70 - 800C


hoc cn do hi lu.
C th dng Chm dt: 120 - = 0.9 1.0
IR cht pepti 150 0
C (trn kn)

Bt u 60
Tt. Cn do 700C
mau ngoi tr Chm dt: 120
SBR SBR loi 1000. 1500C = 1.0
c th dng C th b vng
pepti ha khi T >
1600C
Dng kt hp
vi NR hoc
Xu. Kh cn
BR SBR , nhng
do
Cao Tnh cht gia
Nhit trn Ghi ch
su cng
= 0.9 1.0
Bt u: nhit Dng phng
Tt ty theo phng hay php trn
EPD trc tip hay
loi. Khng cn 1000C
M o ngc
cn do Kt thc: 130
ty theo hm
1400C
lng
Than/ha do
Cao Tnh cht gia
Nhit trn Ghi ch
su cng
Bt u: nhit
thp
= 0.9 1.0
Tt. Cn do Kt thc: 120-
NBR Cho S vo
tng t SBR 1300C
trc
Vng ha khi T
> 1500C
= 1.0
Khng cn do Cho S vo
c trc
Cn trn nhit Dng phng
IIR C th pepti cao
ha bng php trn
peroxid ngc khi
hm lng
n cao
Tt. Loi bin = 0.6 0.7
tnh bng Cho MgO vo
Cn trn nhit
CR mercaptan trc
CAC VAN E KHI
CAN TRON CAO SU
Me tron qua ln so dung tch may.
Me tron qua nho so vi dung tch may.
Hon hp nhieu loai cao su khong eu.
Giai nhiet truc can khong tot.
Can deo khong u hay qua mc.
Th t cac chat phu gia cho vao khong
ung.
Can tron khong u hay qua mc.
O DEO WALLACE
o o bien dang cua mau di mot
ap lc khong oi trong thi gian va
nhiet o qui nh ( TCVN 3975-84).
P = S . R = ( h0 h2)/ (h0 + h1) vi
S : Tnh deo = (h0 h1) / (h0 + h1)
R : Tnh an hoi = ( h0 h2)/ (h0 h1)
h0 chieu cao ban au mau ( mm)
h1 chieu cao mau sau 3 phut dui tac
dung tai
h2 chieu cao mau sau 3 phut hoi phuc.
O NHT MOONEY
Cac bien so:
- Kch thc rotor: 1 ln, 3
nho.
- Nhiet o th nghiem.
- thi gian bat au oc tr so
momen xoan.
ML (1+4) 1000C
THI GIAN T LU
( ISO 667, ASTM DI 646, DIN 52.523).
Thi gian an toan cho hon hp cao

su.
Xac nh bang nht ke Mooney,

rotor nho, nhiet o 120 0C.


Thi gian d nhiet 1 phut, xac

nh thi gian tang 5 n v o


nht Mooney
LC KHANG BAN THANH
PHAM ( GREEN STRENGTH)
Khong tieu chuan hoa nhng
can khi ban thanh pham chu
tac ong bi lc va b bien
dang.
Xac nh bang lc khang keo

co the thi iem chay,


hoac mot o dan dai nhat
nh, hoac trc khi t.
SC DNH (ban thanh
pham)
ay la ac tnh chu yeu e
thanh hnh.
Cha c tieu chuan hoa

Co nhieu cach o nhng thng

da vao lc keo, lc boc tach


hai mau ban thanh pham dan
lai vi nhau ( trong cung nhiet
o, o am, sc ep)

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