Ptotal = p1+ p2

Where,
Ptotal -Total pressure
p1 ,p2 -Partial pressure of component.
 yi P = xi i Pisat ( i= 1,2,..,N)

Where
i = Activity coefficient.
Fugacity: It is derived from Latin, expressed as
fleetness or escaping tendency. It is used
to study extensively phase and chemical reaction
equilibrium.
G = RT ln f +

- Is an constant depends on temperature and nature

of gas.
fugacity has same units as pressure for an ideal gas.
Fugacity coefficient () :
Fugacity coefficient is defined as the ratio of fugacity
of component to its pressure.
=f/P

- Is the measure of non ideal behavior of the gas.

efficient :
It measure the extent to which real solution depart from
ideality.
ln=bx
ln=bx
 Wohls three suffix equation
Margules equation
Van laar equation
Wilson equation
Non random two liquid (NRTL)equation
Universal quasi chemical (UNIQUAC)equation
Universal functional activity coefficient (UNIFAC)
method
 Using slope of ln curves
Using data at mid point
Redlich kister method
Using the coexistence equation
Using partial pressure data