Where,

Ptotal -Total pressure

p1 ,p2 -Partial pressure of component.
Fugacity: It is derived from Latin, expressed as
fleetness or escaping tendency. It is used
to study extensively phase and chemical reaction
equilibrium.
G = RT ln f +

- Is an constant depends on temperature and nature

of gas.
fugacity has same units as pressure for an ideal gas.
Fugacity coefficient () :
Fugacity coefficient is defined as the ratio of fugacity
of component to its pressure.
=f/P

- Is the measure of non ideal behavior of the gas.

Activity(a):
It is defined as the fugacity of the existing condition
to the standard state fugacity
a=f/ fo
Activity coefficient :
It measure the extent to which real solution depart from
ideality.
ln=bx
ln=bx
 Wohls three suffix equation
Margules activity coefficient (UNIFAC) method
 Using slope of ln curves
Using data at mid point
Redlich kister method
Using the coexistence equation
Using partial pressure data
Thank You