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Where,
Ptotal -Total pressure
p1 ,p2 -Partial pressure of component.
x1= p1/ p10
= partial pressure of component /vapour pressure of pure component
Composition in gaseous phase :
y 1 = p 1/ P
= partial pressure of component /total pressure
Raoults law becomes
yiP=xiPisat (i=1,2,3..n)
Where:
yi = Vapor-phase mole fraction.
xi = Liquid-phase mole fraction.
Pi = Vapor pressure of pure species i at the T of the system.
yi P = Partial pressure of species i.
Fugacity: It is derived from Latin, expressed as
fleetness or escaping tendency. It is used
to study extensively phase and chemical reaction
equilibrium.
G = RT ln f +