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  • Where, P - Total Pressure P, P - Partial Pressure of Component

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    The document discusses Raoult's law, which relates the vapor pressure of a component in a mixture to its mole fraction in the liquid phase and its vapor pressure if it existed alone at the same temperature. Specifically, it states that Raoult's law can be expressed as the vapor-phase mole fraction of a component multiplied by the total pressure equals its liquid-phase mole fraction multiplied by its vapor pressure when pure at the system temperature. It also presents a modified form of Raoult's law that includes an activity coefficient term to account for non-ideal behavior in liquid mixtures.

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    DFGH

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    The document discusses Raoult's law, which relates the vapor pressure of a component in a mixture to its mole fraction in the liquid phase and its vapor pressure if it existed alone at the same temperature. Specifically, it states that Raoult's law can be expressed as the vapor-phase mole fraction of a component multiplied by the total pressure equals its liquid-phase mole fraction multiplied by its vapor pressure when pure at the system temperature. It also presents a modified form of Raoult's law that includes an activity coefficient term to account for non-ideal behavior in liquid mixtures.

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    Download as PPTX, PDF, TXT or read online from Scribd
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    6 views3 pages

    Where, P - Total Pressure P, P - Partial Pressure of Component

    Uploaded by

    PRAVIN
    The document discusses Raoult's law, which relates the vapor pressure of a component in a mixture to its mole fraction in the liquid phase and its vapor pressure if it existed alone at the same temperature. Specifically, it states that Raoult's law can be expressed as the vapor-phase mole fraction of a component multiplied by the total pressure equals its liquid-phase mole fraction multiplied by its vapor pressure when pure at the system temperature. It also presents a modified form of Raoult's law that includes an activity coefficient term to account for non-ideal behavior in liquid mixtures.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
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    of 3

    Where,

    Ptotal -Total pressure


    p1 ,p2 -Partial pressure of component.
    x1= p1/ p10
    = partial pressure of component /vapour pressure of pure component
    Composition in gaseous phase :
    y 1 = p 1/ P
    = partial pressure of component /total pressure
    Raoults law becomes

    yiP=xiPisat (i=1,2,3..n)
    Where:
    yi = Vapor-phase mole fraction.
    xi = Liquid-phase mole fraction.
    Pi = Vapor pressure of pure species i at the T of the system.
    yi P = Partial pressure of species i.
    Yi xi i Pisat ( i= 1,2,..,N)

    Where
    i = Activity coefficient.

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