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Chapters 13-14
3) High C Steels contain C between 0.6-1.4 wt% and they are the
hardest, strongest but least ductile of the C steels. They are always
in use in their hardened and tempered condition. They are wear
resistant. They usually contain Cr, vanadium, tungsten and Mo for
higher hardness and used in tools, dies, cutlery dies, shear blades,
etc.
Melting T is b/w
1150-13000C,
which is lower
than steels. This
is why they are
easily melted and
amenable to
casting.
The decomposition
of cementite to
ferrite and graphite
is controlled by the
composition and
rate of cooling.
Graphite formation is fast when
Si concentrations greater than
about 1 wt%. Slow cooling rates
favor the formation of graphite.
Carbon in cast irons is mostly
graphite.
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General Chemistry
Types of cast irons:
a)gray iron: C content: 2.5-4.0 wt % Si content: 1-3 wt%
graphite
ferrite or pearlite
gray iron is weak and brittle in tension (graphite flakes form a stress concentrated
regions), while it has a higher strength and ductility under compressive loads. Base
structures of the machines and heavy equipment exposed to vibration are made of
gray iron. Molten state of the gray iron has lower viscosity at casting temperature,
which makes it possible to cast pieces with intricate shapes. Casting shrinkage is low.
Gray iron is not expensive.
graphite
White Iron and Malleable Iron: If the concentration of Si is low (<1 wt %) and the
cooling rate is fast, then most of the C exists as cementite instead of graphite.
only the surface may have white iron that was chilled
during the casting, gray iron may form at interior parts,
which cool slowly.
White iron is hard brittle, it is not machinable.
Generally white iron is intermediate in the production
of malleable iron.
IE 114-Materials Science and 18
General Chemistry
Heating white iron between 800 and 9000C for a long time in a neutral
atmosphere causes the decomposition of cementite to graphite.
graphite
Bronzes are the alloys of Cu and other elements, such as, tin,
aluminum, silicon and nickel. They are stronger than brass and have
a higher resistance to corrosion.
Magnesium and its alloys: Their major property is their low density (1.7 g/cm3).
They are relatively soft and low elastic modulus. They are difficult to deform
at RT and their m.p. is low. They are chemically instable and may corrode in
marine environments.
Titanium and its alloys: Ti has low density and high m.p. Ti alloys have high
tensile strength and ductile, which makes them machinable. The major
limitation is the chemical reactivity of Ti with other elements at high T. The
resistance to corrosion is high.
Extrusion:a bar
of metal is forced
through a die
orifice by a
compressive force.
The extruded piece
has the desired shape Drawing is the pulling of a metal piece
and thickness. through a die having a tapered bore by
means of a tensile force on the exit side.
IE 114-Materials Science and 26
General Chemistry
When deformation is achieved at a temperature above that at which
recrystallization occurs, the process is termed hot working,
otherwise it is called cold working.
When the piece is hot worked, the deformation is large, which may be
successively repeated since the metal remains soft and ductile.
The energy required for this is less as a result.
Cold working increases the strength of the material while reducing
ductility. The finished product has a better surface quality,
mechanical properties compared to hot worked product.
Welding: two or more metal parts are joined to form a single piece.
Both similar or dissimilar metals can be welded. The joining is
metallurgical rather than just mechanical. Variety of techniques,
such as, arc and gas welding as well as brazing and soldering are
available. During arc and gas welding the parts and filler material
are brought to high temperature to cause both to melt and upon
solidification the filler material forms a fusion joint between the parts.
The region adjacent to weld may experience some alterations in
microstructure and properties. This region is called heat affected
zone.
lower critical T
All alloys have the same hardness (57 HRC) at the quenched end.
Plain carbon 1040 steel has lower hardness and it decreases after a short
Jominy distance.
The decreases in the hardness of the other steels with distance are gradual.
The rate of cooling for a particular quenching treatment depends on the ratio of
surface area to the mass of the specimen. The larger this ratio, the more rapid will
be cooling rate and deeper the hardening effect as a result..