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roperties of Triacylglycerols
1. Hydrolysis
x triacylglycerols undergo stepwise enzymatic
hydrolysis to finally liberate 2 free FA and
glycerols
x catalyzed by lipases
x important for digestion of fat in the GIT and fat
mobilization from the adipose tissues
0. Saponification
x hydrolysis by alkali to produce glycerol and
soaps
Triacylglycerol + 3 NaOH 2 Glycerol + 3R-CooNa (soaps)
3. Rancidity
x term used to represent the deterioration of fats
and oils resulting in an unpleasant taste
x fats with UFA - more susceptible
x occurs when fats are exposed to air, moisture,
light and bacteria
Detabolism of Lipids
U V light
Vit. D Hormones
Bile Acids
Adrenal / gonads
ATHEROSCLEROSIS
acetone
'etone bodies acetoacetate
ë-hydroxybutyrate
1. Conversion of ë-hydroxybutyrate to
acetoacetate yields an NADH molecule, yields 3
AT molecules (by electron transport and
oxidative phosphorylation)