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Introduction
The field of combustion is extremely broad, covering;
• Theoretical
• Experimental
• and Numerical areas
Importance of Combustion in Various
Applications
• Now let us address the question "Why is combustion important?“
• As we know, a very high percentage ( ~80%) of energy comes from
combustion of
• liquids (such as gasoline and hydrocarbon fuels),
• solids (such as coal and wood), and
• gases (such as natural gas composed of largely methane and other
hydrocarbons like ethane, propane, butanes, and pentanes)
Applications of Combustion
Power Generation
• Coal particles are burned in furnaces of power stations to produce steam for driving
turbines in order to generate electricity
• Liquid fuels are used as the source of energy for transportation purposes with
automobiles, aircrafts, ships, etc.
• Natural gases are used for gas turbines, reciprocating engines, etc.
• Solid propellants and fuels are burned in rocket motors for space and missile propulsion
• Fuel cells are used for direct electricity production (strictly speaking, not a combustion
process but involving chemical reactions)
• Waste materials are incinerated
So…..
In general, any theoretical model should be validated by comparison with reliable experimental data before it
is used for prediction and evaluation of the influence of any parameters. Thus the combustion test rig design,
diagnostic measurements, and data analysis are very useful for model validation purpose.
Classification Of Combustion Problems
Usually, classification of combustion problems is based on several factors, including the time and spatial
dependence, the mixing condition of the initial reactants, flow conditions, initial phases of reactants, sites of
reactions, rate of reaction, type of convection, degree of compressibility of the flow, and speed of the
combustion wave. Table 1.1 summarizes the various classifications of combustion problems. This table is
particularly useful to beginners in becoming familiar with the terminology used in chemically reacting flows.
Classification Of Combustion Problems…..
Figure 1.1 illustrates
the essential elements
required to form a
theoretical model. It
also describes the
relationships between
various components
of the model.
It is evident that the
governing equations
are coupled to all
other branches of the
model.
General Structure of a Theoretical Model
Governing Equations for Combustion Modeling (Conservation
and Transport Equations)
Conservation equations consist of
• Conservation of mass (continuity equation)
• Conservation of molecular species (or conservation of atomic species)
• Conservation of momentum (for each independent spatial direction)
• Conservation of energy
• Conservation of angular momentum
Usually the conservation equations are used together with the equations of state to solve for flow property
distributions, including temperature, density, pressure, velocity, and concentrations of chemical species.
The angular momentum components in different directions are solved when the conservation equations of
angular momentum are considered in the model.
General Structure of a Theoretical Model
Governing Equations for Combustion Modeling (Conservation
and Transport Equations)…..
Transport equations are additional equations that are usually required
for turbulent combustion problems; typical examples are
• Transport of turbulence kinetic energy
• Transport of turbulence dissipation rate
• Transport of turbulent Reynolds stresses
• Transport of probability density function
• Transport of moments
Several Basic Definitions
Mole Numbers
• Gaseous molecules and atoms are conveniently counted in terms of
amount of substances or mole numbers. One mole (1 mol or 1 g-mol) of
compound corresponds to 6.02252 x 1023 molecules (or atoms).
Avogadro's Number
NA = 6.02252 x 1023 molecules/mol
Mole Fraction
where ni represents the number of moles of the ith species in the mixture
Mass Fraction
Several Basic Definitions…..
Molecular Weight
This implies
Several Basic Definitions…..
Mass Density (Density)
Equation of State
• For an ideal gas, we can use the following equation of state:
Several Basic Definitions…..
Fuel-Oxidant Ratio, F/O
Equivalence Ratio, Ø
Several Basic Definitions…..
• A premixed gas mixture is said to be stoichiometric if the fuel (e.g.,
CH4 ) and oxidizer (e.g., O2) consume each other completely, forming
only carbon dioxide (C02) and water (H20); i.e.,
• If dry air is used as the oxidizer to react with 1 mole of fuel, then the
mole fraction of the fuel in a stoichiometric mixture with dry air can
be calculated as
Several Basic Definitions…..
• The factor of 4.762 comes from (1 + 79/21), since air contains 21%
oxygen and 79% N2 (with the noble gas portion lumped into
nitrogen). Therefore, the XN2,st is related to XO2,st by
Note that Ψ is closely related to the equivalence ratio (Ø) but they are not identical to each other
Review of Chemical Thermodynamics
• We will briefly introduce and discuss some of the fundamental
concepts of chemical thermodynamics
• To set the scope of the chemical thermodynamics, let us first make a
distinction between heat-transfer theory and thermodynamics
• Heat-transfer theory deals with energy-transfer processes within a
system or between a system and its surroundings due to a
temperature gradient
• Thermodynamics deals with systems in equilibrium and therefore is
applicable to phenomena involving flow and irreversible chemical
reactions only when departures from equilibrium are small
Review of Chemical Thermodynamics
It is useful to define thermodynamic equilibrium by considering the
following three distinct kinds of equilibrium:
• Mechanical equilibrium exists when there are no unbalanced forces in
the interior of a system or between a system and its surroundings.
• Thermal equilibrium exists when all parts of a system are at the same
temperature, which is the same as that of the surroundings.
• Chemical equilibrium exists when a system has no tendency to
undergo a spontaneous change in chemical composition, no matter
how slow.
Review of Chemical Thermodynamics
• When all three kinds of equilibrium are satisfied, the system is said to be in
a state of thermodynamic equilibrium. Under such condition, the analysis
becomes simpler, since the state variables do not change with respect to
time.
• An intensive property is one that is unchanged when the size of the system
is increased by adding to it any number of systems that are identical to the
original system. Some intensive properties are density, pressure,
temperature, specific internal energy u, specific entropy s and so on.
• An extensive property is one that increases in proportion to the size of the
system in such a process. Some extensive properties are volume V, mass m,
total stored energy E, enthalpy H, Gibbs free energy G, kinetic energy KE,
potential energy PE, and so on.
An intensive property can be formed by dividing an extensive property by another extensive
property.