SYSTEM Group 2 Antazo, Francesca Victoria Dionisio, Eunice Anne B. Gutierrez, Ma. Ellah Patricia M. OBJECTIVES The objectives of this experiment are:
to perform steam distillation of immiscible pair of liquids
to compute the partial pressures of the components of immiscible pair of
liquids
to compute the total pressure of the vapor produced from the immiscible pair of liquid from distillation
to construct a liquid-vapor pressure diagram of the two component system
INTRODUCTION Steam distillation • is a process that is used to isolate or to purify volatile materials such as aromatic compounds by adding steam or water to the distillation apparatus.
• This helps to lower the boiling points of the compounds and removes the contaminants from water.
• The process of this kind of distillation isolates the compounds of a
solution by evaporation then condensing the vapor back into liquid. INTRODUCTION Steam generator can be created by heating water in a flask and attaching it to the distillation set- up. The steam from the steam generator is added through the immiscible mixture and it turns to vapor. The vapor is condensed Figure 1. Steam Distillation Set-up and collected after. The mixture condenses as the hot steam passes through it, releasing heat. INTRODUCTION • When two immiscible liquids are heated, the surface of each liquid substances will exert its own vapor pressure as though the other compound of the mixture is not present.
• The vapor pressure of the system will increase as function of
temperature if only one of the components was present.
• The boiling will begin when the total vapor pressure
surpasses the atmospheric pressure. INTRODUCTION A vapor pressure curve is a graph of vapor pressure as a function of temperature. A horizontal line is drawn at a pressure that is equal to the standard pressure. The line intersects the vapor pressure curve to the temperature of Figure 2. Vapor Pressure Curve boiling point of that liquid. METHODOLOGY
In a distilling Attach the
flask, add 50.0 distilling flask in a Heat the mixture mL of toluene condenser. to 80°C . and 25.0 mL of prepare the distilled water. distillation set-up. METHODOLOGY
Prepare heat generator by Record the temperature
placing water in an for every 1.0 mL of erlenmeyer flask and collected distillate until connecting it to the mixture using a glass a total of 10.0 mL of tubing. distillate was collected.