Teknik Reaksi Kimia

Methylcyclohexane
Kelompok 8 Dehydrogenation over
Commercial 0.3 Wt% Pt/Al2O3
Didit Ardi Maulana (1606822213)
Catalyst
Karina Ayuningtyas (1506675661)
Kirana Widiani (1606826880)
Tetra Mutiara (1606828841) Departemen Teknik Kimia
Fakultas Teknik
Syarfina Farisah (1606830606) Universitas Indonesia
 P 10-15b
The dehydrogenation of methylcyclohexane (M) to produce toluene (T) was
carried out over a 0.3% Pt/Al2O3 catalyst in a differential catalytic reactor. The
reaction is carried out in the presence of hydrogen (H2) to avoid coking.
a) Determine the model parameters for each of the following rate laws
1 2 3 4

Use the data in Table P 10-15

b) Which rate law best describes the data? (Hint: Neither K H2 or KM can take on
negative values)
c) Where would you place additional data points?
Model kinetika reaksi katalitik
 Determine the model
parameters for each of
the following rate laws
Determine the model 1

parameters for each of the

following rate laws Menentukan jenis reaksi
REAKSI ELEMENTER
Determine the model Laju reaksi dapat diekspresikan
parameters for each of the seperti berikut:
following rate laws (cont’d) Orde senyawa

atau
Tekanan, karena
P dan C
Adsorpsi : M + S  M•S
berbanding lurus
Reaksi Permukaan: M•S + H2  T•S + H2
•
Dimana,
Desorpsi : T•S  T + S • =1 *Karena reaksi berada dalam
kondisi H2, maka tekanan H2
• =3
akan berpengaruh pada laju
reaksi
 Determine the model
2

parameters for each of the

following rate laws (cont’d) Laju reaksi adsorpsi

Asumsi: •Single Site

 reaksi permukaan.
Laju reaksi permukaan

Adsorpsi : M + S  M.S Laju reaksi desorpsi

Reaksi Permukaan: M.S  T.S + H2
Desorpsi : T.S  T + S
Determine the model
parameters for each of the Site Balance
following rate laws (cont’d)
Asumsi reaksi Laju reaksi permukaan
permukaan
sebagai TPL
Reaksi adsorpsi Laju reaksi desorpsi
Determine the model
Menggunakan Metode Initial Rate
parameters for each of the
following rate laws (cont’d) Belum
terbentuk
 Substitusi persamaan (2), (3) dan
(4) ke persaman (1) Substitusi nilai PT = 0 dan = 0 ke
persamaan (5)
Determine the model
parameters for each of the
following rate laws (cont’d)
Menggunakan Metode Initial Rate

Jika P>> Jika P<<

Dimana,
 3
Determine the model
parameters for each of the
following rate laws (cont’d) Laju reaksi adsorpsi

Asumsi: •Dual Site

 reaksi permukaan.
Laju reaksi permukaan

Adsorpsi : M + 2S  M•S + S Laju reaksi desorpsi

Reaksi Permukaan: M•S + S + H2 T•S + S + H2
Desorpsi : T•S + S  T + 2S
 Determine the model
parameters for each of the Site Balance
following rate laws (cont’d)
Asumsi reaksi Laju reaksi permukaan
permukaan … (6)
sebagai TPL
Reaksi adsorpsi Laju reaksi desorpsi
Determine the model Menggunakan Metode Initial Rate
parameters for each of the
following rate laws (cont’d) Belum
terbentuk
 Substitusi persamaan (7), (8) dan (9) ke
persaman (6) Substitusi nilai PT = 0 dan = 0 ke
persamaan (10)
Determine the model
parameters for each of the
following rate laws (cont’d)
Menggunakan Metode Initial Rate

Jika P>> Jika P<<

Dimana,
 4
Determine the model
parameters for each of the
following rate laws (cont’d) Asumsi reaksi permukaan
Single Site
sebagai TPL
Asumsi:
H2 sekitar mempengaruhi reaksi permukaan Laju reaksi permukaan
H2 bertindak sebagai inhibitor
… (11)

Adsorpsi : M + S  M•S Laju Adsorpsi Methylcyclohexene

: H2 + S  H2•S
Reaksi Permukaan : M•S + H2 T•S + H2
Desorpsi : T•S T + S … (12)
: H2•S  H2 + S
Determine the model parameters for
each of the following rate laws (cont’d)
Laju Adsorpsi H2 Laju Desorpsi H2

Laju Desorpsi Toluene •

Site
Balance

… (13)
… (14)
 Determine the model Menggunakan Metode Initial Rate
parameters for each of the
following rate laws (cont’d) Belum
terbentuk
 Substitusi persamaan (12), (13) dan
(14) ke persaman (11) Substitusi nilai PT = 0 dan = 0 ke
persamaan (15)

… (15) Dimana,
Which rate law best
describes the data?
(Hint: Neither KH2 or KM can
take on negative values)
 Which rate law best
describes the data?
1

 Linearisasi persamaan laju

y a0 a1 x1 a2 x2
Which rate law best 1

describes the data?

 Regresi menggunakan
 Input data ke Ms. Excel Polymath
log r Log PM Log PH2
0,079181 0 0
0,09691 0 0,176091
0,113943 0 -0,30103
0,041393 -0,30103 -0,30103
-0,03621 -0,60206 0
-0,19382 -1 -0,30103
0,103804 0,477121 0,477121
0,10721 0,60206 0
0,09691 0,30103 0,477121
0,113943 0 0,60206
-0,02687 -0,60206 -0,30103
-0,38722 -1,30103 0,30103
Which rate law best 1

describes the data?

Which rate law best
describes the data?
2

 Linearisasi persamaan laju

y a m x
 2
Which rate law best
describes the data?
 Regresi menggunakan
 Input data ke Ms. Excel Polymath

y (P/r) (Pm)
0,833333 1
0,8 1
0,769231 1
0,454545 0,5
0,271739 0,25
0,15625 0,1
2,362205 3
3,125 4
1,6 2 a0 = 0,060882
0,769231 1 k= 16,42524
0,265957 0,25
0,121951 0,05 a1 = 0,76317
Ka = 12,53526
Which rate law best 2

describes the data?

Which rate law best
describes the data?
3

 Linearisasi persamaan laju

y a0 a1 x a2 x 2
 3

Which rate law best

describes the data?
 Regresi menggunakan
 Input data ke Ms. Excel
Polymath

0,833333 1 1
1,2 1 1
0,384615 1 1
0,227273 0,5 0,25
0,271739 0,25 0,0625
0,078125 0,1 0,01
7,086614 3 9
3,125 4 16
4,8 2 4
3,076923 1 1
0,132979 0,25 0,0625
0,243902 0,05 0,0025
 3

Which rate law best

describes the data?
Which rate law best
describes the data?
4

 Linearisasi persamaan laju

 4
Which rate law best
describes the data?
 Regresi menggunakan
 Input data ke Ms. Excel
Polymath

0,833333 1 1
1,2 1 1,5
0,384615 1 0,5
0,227273 0,5 0,5
0,271739 0,25 1
0,078125 0,1 0,5
7,086614 3 3
3,125 4 1
4,8 2 3
3,076923 1 4
0,132979 0,25 0,5
0,243902 0,05 2
Which rate law best 4

describes the data?

 Which rate law best
describes the data?
2

• Rate law (2) best

describes the data,
because the value of
R2 resulted by rate law
(2) is the highest and
the value of Km is
positive.
Where would you
place additional data
points?
Placing
Additional r' y (/r) (PM
M
)
Data Points 2
2
0,5
0,05
0,05
0,1
0,41
0,41
0,64
0,121951
0,121951
0,15625
0,05
0,05
0,1
0,5
1 0,1
0,25 0,64
0,92 0,15625
0,271739 0,1
0,25
1
0,5 0,25
0,25 0,92
0,94 0,271739
0,265957 0,25
0,25
0,5 0,25
0,5 0,94
1,1 0,265957
0,454545 0,25
0,5
1
0,5 1
0,5 1,2
1,1 0,833333
0,454545 1
0,5
1,5
1 1
1 1,25
1,2 0,8
0,833333 1
1
0,5 1 1,3 0,769231 1
1,5
4 1
1 1,25
1,3 0,8
0,769231 1
1
0,5 1 1,213515
1,3 0,769231
0,824052 1
1
4 1 1,244155
1,3 0,769231
1,205638 1
1,5
3 2 1,213515
1,25 1,6
0,824052 2
1
1,269804
1,244155 1,968808
1,205638 2,5
1,5
3
3
3 1,27
2 1,281123
1,25
2,362205
1,6
3
2 Data
2,731978 3,5
1 4 1,269804
1,28 1,968808
3,125 2,5
4 tambahan
3 3 1,27 2,362205 3
1,281123 2,731978 3,5
1 4 1,28 3,125 4
Placing a0 =
k=
0,060882
16,42524
a0 = 0,060882
k= 16,42524
Additional Data
Points (Cont’d) a1 =
Ka =
0,76317
12,53526
a1 =
Ka =
0,76317
12,53526
Using Eexperimental Data
from Scientific Journal
Usman, Muhammad. 2011. “Methylcyclohexane
Dehydrogenation over Commercial 0.3 Wt%
Pt/Al2O3 Catalyst”
 Using Eexperimental Data
from Scientific Journal
rr /r
0,36 1,1 0,012 30 0,36
0,36
0,36 1,1
3 0,012
0,012 30
30 0,36
0,36
Pada suhu 315oC 0,36
0,07 3
1,4 0,012
0,0086 30
8,139535 0,36
0,08
0,07
0,24 1,4 0,0086
0,011 8,139535
21,81818 0,08
0,24
0,72
0,24 1,4 0,013
0,011 55,38462
21,81818 0,68
0,24
0,72 1,4 0,013 55,38462 0,68

Regresi

Adsorpsi : M + S  M.S
Reaksi Permukaan: M.S  T.S + H2
Desorpsi : T.S  T + S
y a m x
Using Eexperimental Data
from Scientific Journal