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22.

14(a) The rate constant for the


decomposition of a certain substance is
2.80 × 10−3 dm3 mol−1 s−1 at 30°C and
1.38 × 10−2 dm3 mol−1 s−1 at 50°C.
Evaluate the Arrhenius parameters of
the reaction.
Given:
K1=2.80 × 10−3 dm3 mol−1 s−1
T1 =30°C (303K)
K2 =1.38 × 10−2 dm3 mol−1 s−1
T2 =50°C (323K)
Required:
Arrhenius parameters (A, − Ea)
Formula(s):
Solution:
Solution:

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