Professional Documents
Culture Documents
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COMPOSITION:-
Calcined calcium sulfate hemihydrate.
CaSO4.1/2 H2O
Anti-expansion agents. - Potassium sulphate
was added which had a tendency to decrease
working time.
Accelerators –accelerators that were added
were
○ Potassium sulphate.
○ Potassium chloride.
Retarders.
○ Colloidal materials/gelatin.
Pigments.
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Uses:
1. Primary impression material.
2. Secondary/corrective impression material.
Water-powder ratio:-
60 ml of water for 100 gm of plaster. Fluidity is
required for recording finer details.
DISADVANTAGES:-
Requires separating medium for pouring and removing
casts. (Varnish, water glass solution).
Dry sensation in patient’s mouth because it absorbs
moisture.
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Thermoplastic Impression Material
It is the temperature at
which they form a rigid
mass
moldable
Soften above this temp Very Soften above/at this temp
and Rigid/sets below this and moldable below this
temp
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Composition:
1. Rosin: 30 parts. Thermoplastic material
2. Copal resin: 30 parts.
3. Carnauba wax: 10 parts.
4. Stearic acid: 5 parts.-Increase plasticity.
5. Talc/ soap stone/ wax: 15 parts. -Decrease flow;
increase strength.
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Copal is a name given to tree resin from the copal
tree Protium copal (Burseraceae) that is particularly
identified with the aromatic resins
Rosin, Is a solid form of resin obtained from pines and
some other plants, mostly conifers, produced by heating
fresh liquid resin to vaporize the volatile liquid terpene
components.
Stearic Acid is a saturated long-chain fatty acid with an 18-
carbon backbone.
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Impression compound is available in
2 forms:
1. Stick form - used for modifying impression
trays. Softening temperature is 700C
2. Sheet form - used to take impressions of the
mouth. Softening temp is 55-600C.
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Modeling Plastic (Compound)
Red brown material in cake form
The most commonly used modeling plastic for
corrected impressions of extension base areas for
partial denture bases and primary impression for
complete denture.
It should be dipped and kneaded until soft and
subjected to no more heat than necessary before
loading the tray and positioning it in the mouth,
then it should be chilled in cold water after each
removal from the mouth
Red, gray, green modeling plastics
in stick form
Used in border molding of impression tray
Red and gray sticks have a higher and broader
working range than do the cake of like color
The modeling plastic are used as a secondary
impression material to record edentulous
ridges in partial denture construction, when
this is done it is generally used only as a mean
of building up the underside of the denture
before recording the tissue with secondary
impression material
Modeling Plastic (Compound)
PROPERTIES
Poor surface detail
High coefficient of thermal expansion
(contraction of up to 0.3% when removed
from mouth to room temperature)
Distorts when removed over undercut areas
Muco displacive
Poor dimensional stability
Can be modified by re-heating
Non toxic and non irritant
Good shelf life
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Thermal conductivity:-
The thermal conductivity is low. Hence has to be
thoroughly cooled before removal.
Average linear contraction of compound on cooling
from mouth temperature to room temperature of 25
degrees is 0.3–0.4 percent. This magnitude of
contraction is unavoidable.
Flow: -
After the compound has softened, and during the
period it is pressed against the tissues, the material
should flow easily to confirm to the tissues so that
every detail and landmark are recorded accurately.
On the other hand, if the amount of flow at mouth
temperature is too great, distortion can occur.
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ADVANTAGES
1. Non irritant and non toxic
2. Reusable (but with re-use the constituents are
leached out)
3. Can be reheated and readapted
4. Can support other materials for wash
impressions
5. Mucocompressive
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DISADVANTAGES
1. Poor dimensional stability
2. Poor surface detail
3. Expansion coefficient
4. Will distort if removed from undercuts
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Different Types :-
1. Brown (Highest Working Temperature)
Stronger At Room Temperature.
Suitable For Extending Short Borders On The Custom
Tray.
Cake Form Is Used For Preliminary Impressions.
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CHEMISTRY
Constituents of a typical zinc oxide eugenol
paste are:
BASE PASTE
Zinc oxide
Inert oils (plasticiser)
Hydrogenated resins (increases setting time and
improves cohesion)
REACTOR PASTE
Eugenol
Zinc acetate (accelerator)
Fillers (talc or kaolin)
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Composition:
TUBE- 1:
1. ZnO (french processed or u.S.P) : 87%
2. Fixed vegetable oil –olive oil/linseed oil: 13%
3. Plasticiser acts as the vehicle and forms paste. It
also helps to masks irritation effect of eugenol.
Tube-2:
1. Oil of cloves (75%-85% eugenol): 12%
2. Gum/ polymerised rosin: 50%.
3. Filler(silica/talc/diatomaceous earth): 20%.
4. Kaolin: 3%.
5. Resinous balsam (Canada balsam): 10%.
6. Accelerator solution & color: 5%.
7. Retarders –Glycerin & petrolatum.
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Resinous balsam is the resinous exudate (or
sap), which forms on certain kinds of trees and
shrubs
Diatomaceous Earth a soft, crumbly, porous
sedimentary deposit formed from the fossil
remains of diatoms.
Kaolin, or China clay, is nearly white in color
The Polymerized Rosin is yellow translucent
irregular solid made from Gum rosin by sulphric
acid and chloride zinc process.
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The 2 pastes come in contrasting colours and
are dispensed in a 1:1 ratio. They are mixed to
give a paste of even colour.
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SETTING REACTION: -
Setting reaction consists of zinc oxide hydrolysis and
a subsequent reaction between zinc hydroxide and
eugenol to form a chelate.
Water is needed to initiate the reaction and it is also
the by-product of the reaction. Hence the reaction is
called as an autocatalytic reaction.
Hence the reaction occurs more rapidly in humid
environment.
The setting reaction is accelerated by the presence of
zinc acetate dihydrate, which can supply zinc ions
more readily. Acetic acid is a more active catalyst for
the reaction. High atmospheric temperatures also
accelerate the setting reaction.
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MANIPULATION
The mixing of two pastes is generally
accomplished on an oil-impervious paper or
a glass mixing slab usually the equal length
of each paste be dispensed onto the mixing
pad,
A flexible stainless steel spatula is typically
used for the mixing procedure. The mixing
is continued for approximately one min or
as directed by the manufacturer.
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The mixture is spread over the preliminary
impression and the tray is carried into the
mouth in the usual manner.
The impression should be held firmly in position
until material has thoroughly hardened.
The accelerating action of saliva on the surface
of the tissues may cause the adjacent surface
of the impression to harden first.
Any disturbance to this stage will result in
warpage.
only when the material has completely
hardened, should the impression be removed
from the mouth. 33
SETTING TIME
In general they set more quickly at higher
temperature and humidities.
Product with long setting time are usually
more affected by changes of temperature and
humidity than product with short setting time.
Clinically this indicate that this materials set
more promptly in the mouth than on the
mixing pad and hot humid condition in the
office results in a short working time.
As such setting time is important since there
must be sufficient time mixing and seating the
impression tray. Once the material in a plastic
condition has been carried to the mouth only
minimal time should elapse before the
impression hardens.
Two setting times ,
Initial and
Final are recognized by the ADA no16 for
dental impression pastes.
also two types of pastes are designated –
Type 1(hard) and
Type 2 (soft) .
the difference between the two type is related to their
hardness after setting.
Initial setting time
Is the period from the beginning of mixing
until the material ceases to pull away or string
out when it surface is touched with metal rod
of specified dimension.
The impression materials should be seated in
the mouth before the initial set, the final set
occurs when the rod fails to penetrate the
surface of the specimen more than 0.2 mm
under a load of 50 gm.
The initial set may vary between 3 to 6 min,
whereas final set should occur within 10 min,
for type 1 and 15 min for type ii pastes.
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CONTROL OF SETTING TIME
If paste sets too slowly, a small amount of
zinc acetate or other accelerators may be added.
Also a small drop of water may be mixed
into the paste containing eugenol before
blending.
When setting time is too short, cooling the
spatula and mixing slab may help increase the
setting time provided the temperature is not
below the dew point.(low temp setting time
becomes longer).
The mixing time affects the setting time to a
very limited extent. The longer the mixing time,
shorter will be the setting time.
NON EUGENOL PASTE
One of the chief disadvantage of ZoE
pastes is the possible stinging or burning
sensation caused by eugenol when it
contacts soft tissues.
Furthermore the ZoE reaction is never
completed, with the result that the free
eugenol may leach out.
Some patients find the taste of eugenol
extremly disagreable and in patients
who wear a surgical pack for several
weeks a chronic gastric disturbance may
result .
Almost any carboxylic acid reacts with
zinc oxide, but only few such acids provide
compound of dental interests.
Orthoethoxybenzoic acid (OEO) is used
in this regard.
The non eugenol cements do not adhere
well to preformed metal crowns as the
eugenol containing cements, and they are
slower setting.
The non-eugenol cements do not soften
provisional acrylic crowns.
CONSISTENCY & FLOW:
Material should be
1. Homogenous.
2. Flow uniformly.
3. Mucostatic.
4. Flow related to setting time.
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DIMENSIONAL STABILITY: -
The dimensional stability of impression
pastes is quite satisfactory. A negligible
shrinkage (<0.1%) may occur during
hardening. Impressions can be preserved
indefinitely* without change in shape.
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ADVANTAGES:-
1. Adheres well to tray.
2. It is sufficiently fluid to record fine details of tissues.
3. Does not undergo any dimensional change during setting
process.
4. Has adequate working time & setting time.
5. Sufficient resistance.
6. It is compatible with gypsum products.
7. No separating medium required for gypsum products.
8. It has A satisfactory shelf life.
9. It is non-toxic.
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DISADVANTAGES:-
1. Burning/tingling sensation of eugenol is
a major disadvantage.
2. Persistent taste of eugenol added
disadvantage.
3. As it adheres to tissues, lips should be
coated with petrolatum jelly.
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Impression Materials
Are those that remain in an elastic or flexible state after they have set and
have been removed from the mouth
Hydrocolloids
Reversible vs. irreversible hydrocolloids
All hydrocolloids are dimensionally stable only
during a brief period of time
They are hydrophilic materials so can gain water
and expand (imbibition), so must not be immersed
in water
They lose water rapidly and shrink if exposed to
air
Hydrocolloids
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TYPES
Type1-fast setting- 1.5-3 min
Type 2-normal setting- 3-4.5min
MODE OF SUPPLY
It is supplied as powder that is packed.
a. in bulk or in tins, or in sachets or
b. in pre weighed individual containers
A plastic scoop is supplied, or dispensing the
bulk powder and a plastic and a plastic cylinder
is supplied for measuring the water required for
the bulk or the pre weighed alginate powder.
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COMPOSITION
The chief ingredient is the soluble alginate
such as the potassium alginate or tri-ethanal-
amine alginate when mixed with water they
form a viscous gel.
Calcium sulfate dehydrate is used as a
reactor. They react with the soluble alginate
to form an in-soluble calcium alginate gel.
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A TYPICAL MANUFACTURE’S FORMULA
FOR THE ALGINATE AS FOLLOWS
COMPONENT FUNCTION WEIGHT
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GELATION PROCESS
The typical sol-gel reaction can be described
simply as a reaction of soluble alginate with
calcium sulfate to form an in soluble calcium
alginate gel.
the production of calcium alginate is so rapid
that it does not allow sufficient working time,
thus a third water soluble salt, such as tri
sodium phosphate, is added to prolong the
working time .
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Hydrocolloids
They should be poured immediately no more than
15 minutes delay and stored during this period in
a saturated atmosphere (wrapping impression in
a damp paper towel)
Hydrocolloids exhibit a phenomenon known as
syneresis , which is associated with the giving off
a mucinous exudates that will affect the gypsum
material and produce soft or chalky cast surface
This can be prevented by pouring the cast
immediately and using some chemical
accelerators as potassium sulfate.*
The strategy is that the calcium sulfate will react
with the tri sodium phosphate in preference to the
sodium alginate and delay the formation of the
soluble calcium alginate .the reaction is as follows.
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GEL STRUCTURE
The gel structure can be envisioned as a
brush heap of calcium alginate fibril network
enclosing unreacted sodium alginate sol,
excess water, filler particles and reaction by
products, such as sodium sulfate and calcium
phosphate.
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Advantages of Alginate
No smell, no taste
Step-by-step Procedure for Making
Alginate Impression
Tray Selection
Large enough with 5mm
of clearance to provide a
4- to 5-mm thickness of
impression material
between the teeth &
tissue, & the tray
Hydrocolloid requires
bulk for accuracy,
strength and stability
Build up the palatal
portion of the maxillary
impression tray with
wax or modeling
plastic *
Material can be
syringed into the palate
Smooth with a finger,
or voids may occur
The lingual flange of
the mandibular tray
may need to be
lengthened with wax in
the retromylohyoid
area or to be extended
posteriorly, but it rarely
ever needs to be
lengthened elsewhere
Place the measured
amount of water (at
70° F) in a clean,
dry, rubber mixing
bowl (600-ml
capacity). Add the
correct measure of
powder
Stir rapidly against
the side of the bowl
with a short, stiff
spatula. This
should be
accomplished in
less than 1 minute.
Place the patient in an upright
position, with the arch to be
impressed nearly parallel to the floor.
Ask the patient to rinse his or her
mouth with cool water to eliminate
excess saliva while the impression
material is being mixed and the tray
is being loaded.
After loading the tray, remove the
gauze with the topical anesthetic
and quickly place (rub) some of the
impression material on any critical
areas using your finger (areas such
as rest preparations and abutment
teeth).
Place the anterior portion of the
tray first, then seat the posterior
of the tray
Mold the vestibular area
Pull on the cheeks and lips to
activate muscles and frena
Support the tray
during setting - do
not leave the
patient
Movement causes
distortion *
Once seal broken, remove
quickly (to avoid permanent
deformation)
Evaluate impression
Pour within 15 minutes
Rinse thoroughly with water
Gently shake to remove excess
water
Spray with disinfectant to
coat all surfaces, and seal
in a bag for 15 minutes
Common Pitfalls and Solutions in
Impression Making
Common Pitfalls and Solutions in
Impression Making
Common Pitfalls and Solutions in
Impression Making
Common Pitfalls and Solutions in
Impression Making
Common Pitfalls and Solutions in
Impression Making
Common Pitfalls and Solutions in
Impression Making
Pitfall: Removing tray improperly.
Solution: Don’t use handle, and break
suction over premolar area and pull tray
down.
Corrected Cast
Modified Cast
Altered Cast Impressions
Impression of residual ridge
Custom impression tray attached
to the framework
Purpose
1 mm wax relief
Heat and fully seat the framework
3. Separator (Tinfoil substitute (Alcote) or model
release agent) +Acrylic tray adaptation
4. Check Seating
Fulcruming or tissue
compression
Spring back and lack of tissue
contact
8. Remove & Inspect Impression
Absence of voids
Minimal burnthrough
Covers supporting
tissues
Fully seated, etc.
9. Send to Laboratory
Lab Steps
Section residual ridge from
cast
Ensure no contact between
impression & cast
Place retentive grooves in
cast
Sticky wax in place
Lab Steps
Box impression
Ensure water tight seal
Seal retainer, major &
minor connector borders
Pour new ridge areas in
different color stone
Pour new ridge areas in different color
stone
Problems with the Altered Cast
Technique