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• As this training material focuses on the general information only, it is anticipated for trainee without
background knowledge. Experienced staff, however, can refer the materials as reference guidelines.
• Practical training followed with an assessment is highly recommended to testify and reinforce the
understanding of the trainee on the subsequent test.
• The procedure is intended for use in the range of free and hydrolysed
formaldehyde on the fabric between 16mg/kg and 3500mg/kg when
determined by this method. The lower limit is 16mg/kg.
2. Put the weighed pieces into 250ml flask with stopper and add 100ml of water.
3. Stopper tightly and place in a water bath at 40 ± 2°C for 60 ± 5 min with
shaking at least every 5 min.
Important Notes:
Important Notes
• Exposure of the developed yellow colour to direct sunlight for a period of time will
cause some fading. Care should be taken to protect the tubes such as by covering
them with a formaldehyde free enclosure
5 Confirmation Test Free and Hydrolized Formaldehyde (ISO 14184-1)
Amount of the formaldehyde extracted for each specimen (F) to the nearest mg/kg
𝐶×𝑉
F = × 𝐷. 𝐹
𝑊
Where,
C = Concentration of formaldehyde in sample solution as read from
calibration graph , mg/L
V = Volume of water extract, 100 mL
W = Sample weigh, 1 g / 2.5 g
D.F. = Dilution factor
For Example:
1. Calibration
curve
development
2. Measure
the absorbance 3. Find the
of aliquot intersection point
4. Formaldehyde
content in the
aliquot
Thank you.
14 3/31/2019
1
Released Formaldehyde (Vapor Absorption
Method)/ISO 14184-2
Scope & Principle
Important Notes:
• A = corrected absorbance
• As = measured absorbance of the test specimen (Tube A)
• Ab = measured absorbance of the blank reagent (Tube C)
• Ad = measured absorbance of the blank specimen (Tube D), only in case of discoloration or
the contamination
Amount of the formaldehyde extracted for each specimen (F) to the nearest mg/kg
F = (C x 100) / W
• C = concentration of formaldehyde in solution (in mg/l) as read form the calibration graph
• W = Mass
JIS test method A -For babies or infants within 24 months after birth
JIS test method B-Over 24 months .
Textile products for Infants and babies (Infants and babies means the age within 24 months)
including underwear, nappies, bedding, gloves, socks, clothing etc.
JIS L 1041: Preparation of test specimens
The test portion should be taken from extremities and the central part to ensure its
homogeneity.
For Method A, weigh 2.50 ± 0.01 g of the sample and put it into a 200 ml Erlenmeyer
flask with stopper.
For Method B, weigh 1.00 ± 0.01 g of the sample and put it into a 200 ml Erlenmeyer
flask with stopper.
JIS L 1041: Preparation of the aqueous extract
Pipette 100 mL of water into a flask containing test sample and sealed with stopper.
Place the flask into a shaking water bath at 40 ± 2 oC (4.11). Providing a to-and-fro
movement at a rate approximately 20 min-1
Filter the aqueous extract by a filter paper (4.8) when the solution is still warm
JIS L 1041: Color development of sample solution
Cool down the vials at room temperature for 30 minutes after shaking.
JIS L 1041: Color development in working standards solution
& calibration check solution
Pipette 5 mL of each standard working solution into 5 reaction vials respectively.
Pipette 5 mL of Nash reagent into each of vials.
Pipette 5 mL of 0.3 mg/L calibration check standard (5.5.1) into a reaction vial.
Pipette 5 mL of Nash reagent (5.2.18) into the vial.
Calculations
Comparison of ISO 14184-1, JIS S & B (L 1041 ), ISO 14184-2, AATCC 112, & BS 6806
standards on formaldehyde
ISO 14184-1 JIS A & B (L1041) ISO 14184-2 AATCC 112 BS 6806 Part 2 & 3
Objects
For free For free For released For released For free & released
Scope
formaldehyde formaldehyde Formaldehyde Formaldehyde formaldehyde
2.0g for free
2.5 g for A formaldehyde
Weight of specimen 1g 1g 1.0 g
1.0 g for B 1.0g for released
formaldehyde
25oC for free
Extraction formaldehyde
40oC 40oC 49 ± 2º C 65oC
temperature 49oC for released
formaldehyde
20 min or free
20 hours ± 15 formaldehyde
Extraction time 1 hr 1 hr 4 hrs
minutes 20 hrs for released
formaldehyde
Wavelength for
absorbance 412 nm 415 nm 412 nm 412 nm 570 nm
measurement