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eff
Oe erg J J
mc
eh
g
eff
/ ) 1 (
4
+ =
t
B
J J g ) 1 ( + =
Quantum Theory of Paramagnetism
. Brillouin function
- The procedure of derivation is the same as Langavin, except that.
(1)
(2)
u
B
J
H
M
g = cos
}
J
J
J
M
du
t
) (
0
H
M
g
E
B
J P
=
Boltzmann factor =
e e
kT H
M
g kT
E
B
J P
/ /
=
=
J
J
kT H g
J
J
kT H g
B
J
e
e M
B
J
B
J
M
M
g
n
/
/
)
`
|
.
|
\
|
+ +
=
J
a
J J
J
J
J
ngM
a
B
J
2
`
coth
2
1
2
1 2
coth
2
1 2 `
kT
H
kT
H gM
a
H B
J
= = `
,
A special case
If
kT
J J
kT H g M
B
B J
3
) 1 ( g
then
If
2 2
+
=
<<
= M/H
0
Quantum Theory of Paramagnetism
When a` is small,
`) , (
3
) 1 `(
`) , (
a J B ngJ M
J
J a
a J B
B
=
+
=
kT
H n
eff
3
2
=
T
C
AkT
N
H
M
eff
= = = =
3
2
k
_
Ak
N
C
eff
3
2
=
X =?
For detail expressions follow S.O. Pillai book
Quantum Theory of Paramagnetism
J
a
J
a
J
J
J
J
M
M
2
`
coth
2
1
2
1 2
coth
2
1 2
`
0
|
.
|
\
|
+ +
=
Brillouin function, B(J,a)
1) If J = infinite, B(J,a`) =
`
1
` coth
a
a
) ( ) , ( a L a J B =
2) If J=1/2(only spin contribution),
` tanh a`) B(J,
0
a
M
M
= =
. Paramagnetic materials
atoms or ions which have a net magnetic moment
because of noncancellation of the spin and orbital component.
Salts of the transition elements
- Incomplete inner shells
- Magnetic moments due almost to spin(g 2)
- This metal salts obey the Curie or Curie-Weiss law with a small
~
Salts and oxides of the rare earths
Rare-earth elements