PROJECT : POLYACRILIC ACID PRODUCTION

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REMEMBERING... Our project is aimed to create new marketing area by producing poly acrylic homo polymer which is widely used in ceramic, textile ,paper industries. By coming true the this object, we will have decreased all costs for the companies having dependency on that chemical and contributed economy of our country.

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For this purpose...

It is needed to get neccessary instruments for

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What have been done so far...

Literature scanning. studies,searching, industries consuming PAA in Turkey,aim of usage. process analysis. materials source. a new market.
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Feasibility

Production Raw

Defining

Now:

PROJECT ORGANISATION TEAM

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Name

Servis

Cost

Project preparation, monitoring and PRODEV Consulting finalization for Engineering TUBTAK STANDARDS

10.000 TL

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OUR INSTRUMENTS & EQUIPMENTS

Gel

Permeation Chromatography

Gas

Chromatography
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Market Analysis Of Instruments &

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INSTRUMENT

TECHNICAL PROPERTIES

OBTECTIVES

COST

GPC (gel permeation RI and Light chromatogaphy) Scattering Detectors, GPCV 2000 WATERS Aqueous Phase Column, OmniSEC Conventional Calibration etc Gas Chromatography Perkin Elmer XL Autosystem GC Flame Ionization detector, Microprocessorcontrolled, injection system

measurement of acrylic acid molecular $7,750 weight& molecular distribution (www.labx.com)

measurement of amount of remaining acrylic acid in polyacrylic acid

$10,500 (www.labx.com)

Karl Fischer Volumetric Titrator 6Hanna Instruments HI 903 Karl Fischer Volumetric Titrator for Moisture Determination

115V/230V, +/determination of 0.1mV Accuracy, 1 water amount of ppm Resolution sample of polymers

$6,256.59 (www.amazon.com)

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INSTRUMENT

TECHNICAL PROPERTIES

OBTECTIVES

COST

JK-PWS-Q HPLC grade Reverse osmosis water ability deionized pure biological water system filtration, reverse osmosis system Automatic Interface Tensiometer Adopt pccontrolled, automatic measuring, display data curve, print test report. new laser, IR source, complete optical and electronic calibration. 5/7/12

suppiling $2,298.95 ultrapure water (www.aliexpress to GPC .com)

Tensiometric Analysis

$4,500 (www.alibaba.c om)

PerkinElmer RECONDITIONE D FTIR (Fourier transform infrared)

chemical $ 8,200 compositions of (www.labx.com) polymer samples

INSTRUMENT

TECHNICAL PROPERTIES

OBTECTIVES Rheological Analysis

COST

STRESSTECH HR Concentric Rheometer System Cylinder temperature cells. Parallel plate

$31,900.00 (www.labx.com)

Differential Scanning Calorimeter (DSC)

Thermal properties & Crystallinity

$310.00 (www.labx.com)

Malvern Zetasizer Measure of particle size, zeta potential, molecular weight..

Zeta Potential values

$4,795 (www.labx.com)

TOTAL COST

$76,509 (135.42 TL)*

(*1 ABD Dolar = 1,77 TL)

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NUMBER Acrylic Resin Reactor Kettle (1000L)

MANUFACTURER

COST

Foshan Nanhai Jinchangtai Machine Equipment (China)

US $ 1,000

Storage Tanks (500L)

10

Wenzhou L&B Fluid Equipment Co., Ltd. (China) US $ 500

TOTAL

US $ 6,000 (10.620 TL)*

(*1 ABD Dolar = 1,77 TL)

source:www.alibaba.com

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RAW MATERIALS
Ammonium Acrylic Water

Persulphate

Acid

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Tianjin Flourish Chemical Co., Ltd.

Ammonium Persulphate US $ 1,530 - 1,700 / Ton

COMPANY

PRICE

Pinghe Yongsheng Chemical Industrial Co., US $ 660 - 699 / Ton Ltd. US $ 680 - 750 / Ton Sanming Zhan Hua Chemical Industrial Co., Ltd US $ 100 - 250 / Ton Hebei Shengweilong Commercial & Trade Co., Ltd US $ 850 - 950 / Ton

Zibo Pulisi Trading Co., Ltd.

Source: www.alibaba.com

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Acrylic Acid
COMPANY PRICE Changshu Jinfeng Chemicals Co., Ltd. US $ 1,900 - 2,200 / Metric Ton (China) Qinghe County Longmeikang Cashmere Products - 1,900 / Metric Ton US $ 1,500 Co., Ltd (China) Synchem International Co., Ltd. (China) Manav Bo Chem Impex Pvt Ltd (India) US $ 3,000 4,000 / Metric Ton US $ 450 - 750 / Metric Ton

Source: www.alibaba.com

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UTULITIES
Water

- 7.15 TL/TON (IZSU) 29.578 Kr/kW h (AYEDA)

Electricity

Natural

Gas - 0.81TL/m3 (IGDA)

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Needed amount (kg) /batch Acrylic Acid Amonium persulfhate Water

960 kg/batch 72 kg/batch 1380 kg /batch

Cost TL /batch
850 TL
(US $ 480/batch)*

12.8 TL

(US $ 7.2/batch)*

9.8 TL /batch 872.6 TL /batch

Total
(*1 ABD Dolar = 1,77 TL)

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ENVIROMENTAL EFFECTS OF POLYACRYLIC ACID PRODUCTION

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The 25 different chemicals, one of them is acrylic acid is wanted to stock in a new plant planning to established near by Yalova by a Holland company VOPAK. These chemicals are reported to notice environmental bad-side effects by CED. In the report for acrylic acid it says:

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Easily Very Skin Very

reach the flash point.

dangerous when inhaling contant gives body burns

dangerous in case any leaking to the water-loving organisms.

Source:http://t24.com.tr/haber/yalovayi-bekleyen-buyuk-tehlike/170636

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Effects of the Environment

Acrylic

acid emitted into the atmosphere will react with photo chemically produced hydroxyl radicals and ozone, resulting in rapid degradation.

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When

released into water, acrylic acid readily biodegrades. The fate of acrylic acid in water depends on chemical and microbial degradation.

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Human Exposure
No

data on general population exposure are available. However, consumers may be exposed to unreacted acrylic acid in household goods such as polishes, paints and coatings, rug backing, plastics, textiles and paper finishes.

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Inhalation

and contact with skin are important routes of occupational exposure. of the route of exposure, acrylic acid is rapidly absorbed and metabolized.

Regardless

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Effects on Animals
Most

data indicate that acrylic acid is of low to moderate acute toxicity by the oral route, and of moderate acute toxicity by the inhalation and dermal routes.

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Acrylic

acid is a strong corrosive agent to many metals, such as unalloyed steel, copper and brass. Frequently the hydrolysis of such metallic materials generates a deep discoloration in acrylic acid.

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Safety in Use
Acrylic

acid should only be handled in wellaerated and well-ventilated places.

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If

exposure to concentrated vapor can not be excluded (as in the case of an accident), self-contained breathing apparatus or air supply masks must be worn.

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In

areas where a release of acrylic acid is possible, eye protection devices, face shields, neoprene gloves and rubber boots should be worn.

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chemical suit with a selfcontained breathing apparatus is strongly recommended if larger spills or emissions have to be cleared.

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Explosion and Fire Hazards

Acrylic

acid has a flash point of 54-68C and does not form exposable vapor mixtures at ordinary ambient temperatures.

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During

transfer from one container into another, the containers should be electrically interconnected and properly grounded. Splashing into a tank should be avoided by using a dip tube.

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Since

acrylic acid and water are miscible in any proportion, water can be used to extinguish fires. fires can be fought with carbon dioxide or dry chemical extinguishers.

Small

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Thanks all for your attention

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